Players who scored on their first appearance at Anfield.
| Player | Date | Result | Opposition | Competition |
|---|---|---|---|---|
| Hugo Ekitike | 15 Aug 2025 | 4 - 2 | Bournemouth | Premier League |
| Lewis Koumas | 28 Feb 2024 | 3 - 0 | Southampton | FA Cup 5th round |
| Kaide Gordon | 09 Jan 2022 | 4 - 1 | Shrewsbury Town | FA Cup 3rd round |
| Diogo Jota | 28 Sep 2020 | 3 - 1 | Arsenal | Premier League |
| Virgil Van Dijk | 05 Jan 2018 | 2 - 1 | Everton | FA Cup 3rd round |
| Sadio Mané | 10 Sep 2016 | 4 - 1 | Leicester City | Premier League |
| Sheyi Ojo | 20 Jan 2016 | 3 - 0 | Exeter City | FA Cup 3rd round replay |
| Christian Benteke | 17 Aug 2015 | 1 - 0 | Bournemouth | Premier League |
| Jordan Rossiter | 23 Sep 2014 | 2 - 2 | Middlesbrough | League Cup 3rd round |
| Daniel Sturridge | 19 Jan 2013 | 5 - 0 | Norwich City | Premier League |
| Fabio Borini | 09 Aug 2012 | 3 - 0 | Gomel | Europa League 3QR 2L |
| Luis Suarez | 02 Feb 2011 | 2 - 0 | Stoke City | Premier League |
| Glen Johnson | 19 Aug 2009 | 4 - 0 | Stoke City | Premier League |
| Andriy Voronin | 01 Sep 2007 | 6 - 0 | Derby | Premier League |
| Fernando Torres | 19 Aug 2007 | 1 - 1 | Chelsea | Premier League |
| Gabriel Paletta | 25 Oct 2006 | 4 - 3 | Reading | League Cup 3rd round |
| Mark Gonzalez | 09 Aug 2006 | 2 - 1 | Maccabi Haifa | Champions L. 3rd QR. 1st leg |
| Craig Bellamy | 09 Aug 2006 | 2 - 1 | Maccabi Haifa | Champions L. 3rd QR. 1st leg |
| Luis Garcia | 11 Sep 2004 | 3 - 0 | WBA | Premier League |
| Milan Baros | 21 Sep 2002 | 2 - 0 | WBA | Premier League |
| El Hadji Diouf | 24 Aug 2002 | 3 - 0 | Southampton | Premier League |
| Layton Maxwell | 21 Sep 1999 | 4 - 2 | Hull City | League Cup 2nd round 2L |
| Øyvind Leonhardsen | 25 Oct 1997 | 4 - 0 | Derby | Premier League |
| Paul Ince | 13 Aug 1997 | 1 - 2 | Leicester City | Premier League |
| Stan Collymore | 19 Aug 1995 | 1 - 0 | Sheffield Wednesday | Premier League |
| Nigel Clough | 14 Aug 1993 | 2 - 0 | Sheffield Wednesday | Premier League |
| Paul Stewart | 19 Aug 1992 | 2 - 1 | Sheffield United | Premier League |
| David Speedie | 09 Feb 1991 | 3 - 1 | Everton | 1st Division |
| John Barnes | 12 Sep 1987 | 2 - 0 | Oxford United | 1st Division |
| Gary Ablett | 18 Apr 1987 | 3 - 0 | Nottingham Forest | 1st Division |
| John Aldridge | 28 Feb 1987 | 1 - 0 | Southampton | 1st Division |
| Paul Walsh | 27 Aug 1984 | 3 - 0 | West Ham United | 1st Division |
| Ronnie Whelan | 03 Apr 1981 | 3 - 0 | Stoke City | 1st Division |
| Avi Cohen | 03 May 1980 | 4 - 1 | Aston Villa | 1st Division |
| Sammy Lee | 08 Apr 1978 | 3 - 2 | Leicester City | 1st Division |
| Kenny Dalglish | 23 Aug 1977 | 2 - 0 | Newcastle United | 1st Division |
| David Fairclough | 04 Nov 1975 | 6 - 0 | Real Sociedad | UEFA Cup 2nd round 2L |
| Ray Kennedy | 07 Sep 1974 | 5 - 2 | Tottenham | 1st Division |
| Peter Cormack | 09 Sep 1972 | 4 - 2 | Wolves | 1st Division |
| Kevin Keegan | 14 Aug 1971 | 3 - 1 | Nottingham Forest | 1st Division |
| John McLaughlin | 22 Aug 1970 | 4 - 0 | Huddersfield Town | 1st Division |
| Alec Lindsay | 16 Sep 1969 | 10 - 0 | Dundalk | EFC 1st round 1st leg |
| Alun Evans | 21 Sep 1968 | 4 - 0 | Leicester City | 1st Division |
| Bobby Graham | 14 Sep 1964 | 6 - 1 | KR Reykjavík | European Cup Pre-Round 2nd L |
| Kevin Lewis | 20 Aug 1960 | 2 - 0 | Leeds United | 2nd Division |
| Dave Hickson | 07 Nov 1959 | 2 - 1 | Aston Villa | 2nd Division |
| Roger Hunt | 09 Sep 1959 | 2 - 0 | Scunthorpe United | 2nd Division |
| Alan Banks | 03 Sep 1958 | 5 - 0 | Brighton & Hove Albion | 2nd Division |
| Tony McNamara | 21 Dec 1957 | 4 - 3 | Bristol City | 2nd Division |
| Jimmy Melia | 17 Dec 1955 | 5 - 2 | Nottingham Forest | 2nd Division |
| Tony Rowley | 19 Apr 1954 | 4 - 1 | Middlesbrough | 1st Division |
| Alan Arnell | 05 Dec 1953 | 5 - 2 | Blackpool | 1st Division |
| Louis Bimpson | 03 Apr 1953 | 2 - 1 | Cardiff City | 1st Division |
| Brian Jackson | 10 Nov 1951 | 1 - 1 | Bolton Wanderers | 1st Division |
| Jack Smith | 29 Sep 1951 | 2 - 0 | Derby | 1st Division |
| Billy Liddell | 07 Sep 1946 | 7 - 4 | Chelsea | 1st Division |
| Cyril Done | 02 Sep 1939 | 1 - 0 | Chelsea | 1st Division |
| Ron Jones | 26 Mar 1938 | 2 - 0 | Manchester City | 1st Division |
| Ted Harston | 01 Sep 1937 | 3 - 2 | Portsmouth | 1st Division |
| Bob Glassey | 07 Dec 1935 | 2 - 1 | Preston North End | 1st Division |
| Berry Nieuwenhuys | 30 Sep 1933 | 3 - 2 | Everton | 1st Division |
| Sam English | 30 Aug 1933 | 1 - 1 | Stoke City | 1st Division |
| Alf Hanson | 01 Feb 1933 | 1 - 3 | Middlesbrough | 1st Division |
| Ted Crawford | 27 Aug 1932 | 5 - 1 | Wolves | 1st Division |
| Ted Savage | 26 Sep 1931 | 4 - 0 | Grimsby Town | 1st Division |
| Gordon Gunson | 22 Mar 1930 | 2 - 0 | Aston Villa | 1st Division |
| Billy Millar | 25 Aug 1928 | 3 - 0 | Bury | 1st Division |
| Albert Whitehurst | 25 Aug 1928 | 3 - 0 | Bury | 1st Division |
| Willie Devlin | 31 Aug 1927 | 5 - 1 | Bury | 1st Division |
| Tom Reid | 01 May 1926 | 2 - 2 | Sheffield United | 1st Division |
| Fred Baron | 21 Mar 1925 | 3 - 0 | Burnley | 1st Division |
| Jimmy Walsh | 29 Aug 1923 | 6 - 2 | Birmingham | 1st Division |
| Cyril Gilhespy | 01 Apr 1922 | 2 - 0 | Oldham Athletic | 1st Division |
| Peter McKinney | 09 Oct 1920 | 2 - 2 | Sheffield United | 1st Division |
| Harry Chambers | 01 Sep 1919 | 2 - 3 | Arsenal | 1st Division |
| Fred Pagnam | 31 Oct 1914 | 7 - 2 | Tottenham | 1st Division |
| Billy Banks | 18 Mar 1914 | 3 - 0 | Chelsea | 1st Division |
| Arthur Metcalf | 19 Oct 1912 | 4 - 1 | Blackburn Rovers | 1st Division |
| John Tosswill | 04 Sep 1912 | 2 - 0 | Oldham Athletic | 1st Division |
| Joseph Brough | 17 Sep 1910 | 2 - 3 | Nottingham Forest | 1st Division |
| Jimmy Stewart | 11 Sep 1909 | 3 - 1 | Blackburn Rovers | 1st Division |
| John McDonald | 11 Sep 1909 | 3 - 1 | Blackburn Rovers | 1st Division |
| Harold Fitzpatrick | 12 Oct 1907 | 1 - 0 | Sunderland | 1st Division |
| Tom Chorlton | 29 Oct 1904 | 5 - 0 | Grimsby Town | 2nd Division |
| George Livingstone | 06 Sep 1902 | 5 - 2 | Blackburn Rovers | 1st Division |
| Bill White | 14 Sep 1901 | 2 - 2 | Everton | 1st Division |
| Charlie Satterthwaite | 23 Dec 1899 | 5 - 2 | Glossop FC | 1st Division |
| Tommy Robertson | 11 Apr 1898 | 4 - 0 | The Wednesday | 1st Division |
| Jack Cox | 12 Mar 1898 | 2 - 0 | Notts County | 1st Division |
| Willie Michael | 10 Oct 1896 | 3 - 0 | Nottingham Forest | 1st Division |
| Ben Bull | 25 Jan 1896 | 6 - 1 | Lincoln City | 2nd Division |
| Fred Geary | 07 Oct 1895 | 6 - 1 | Crewe | 2nd Division |
| Frank Becton | 25 Mar 1895 | 2 - 3 | Sunderland | 1st Division |
| David Hannah | 17 Nov 1894 | 2 - 2 | Everton | 1st Division |
| Jimmy Ross | 13 Sep 1894 | 1 - 2 | Bolton Wanderers | 1st Division |
| Albert Worgan | 03 Mar 1894 | 3 - 1 | Burton Swifts | 2nd Division |
| Harry Bradshaw | 04 Nov 1893 | 5 - 1 | Newcastle United | 2nd Division |
| Douglas Dick | 04 Nov 1893 | 5 - 1 | Newcastle United | 2nd Division |
| David Henderson | 23 Sep 1893 | 3 - 1 | Birmingham | 2nd Division |
| Patrick Gordon | 09 Sep 1893 | 4 - 0 | Lincoln City | 2nd Division |
| John McCartney | 29 Oct 1892 | 9 - 0 | Newtown | FA Cup 2nd Qualifier |
| Hugh McQueen | 29 Oct 1892 | 9 - 0 | Newtown | FA Cup 2nd Qualifier |
| John Miller | 24 Sep 1892 | 4 - 0 | Bury | Lancashire League |
| Jock Smith | 03 Sep 1892 | 8 - 0 | Higher Walton | Lancashire League |
| Joe McQue | 03 Sep 1892 | 8 - 0 | Higher Walton | Lancashire League |
| Jonathan Cameron | 03 Sep 1892 | 8 - 0 | Higher Walton | Lancashire League |
| Malcolm McVean | 03 Sep 1892 | 8 - 0 | Higher Walton | Lancashire League |
| Jim McBride | 03 Sep 1892 | 8 - 0 | Higher Walton | Lancashire League |